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When hairspray spills on the carpet, it's imperative one acts quickly before the stain hardens. If you're not fast enough, all is not lost, it's really not difficult to remove carpet stains such as this. Ask yourself, what happens when hair spray builds up in my hair? You shampoo it, right? The same method will work here. For cleaning carpet of hardened hairspray, just blot with a little clarifying shampoo and water. In just about every case, this will be enough to do the trick. Just keep blotting until all of the hairspray and its stickiness is removed.