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To remove your cayenne pepper stain, it is very important to use cold water, as heat will set the stain. You should be able to remove the stain by soaking the item in cold water with one cup of dishwasher detergent (powder for your machine) dissolved in it. Allow to soak for a few hours, then launder as usual, rinsing in cold water with 1/2 cup of white vinegar added.