Urine can saturate absorbent materials such as carpet, well beyond the surface area that can effectively be cleaned. It is extremely difficult to remove all of the urine from the carpet fibers, carpet backing and padding underneath, thereby creating ideal conditions for bacteria and mold growth (and thus malodors). However, you might not be ready to replace your items just yet. First, blot up as much of the urine as possible with an absorbent white cloth.
The newest technology uses peroxide and detergents to penetrate the soiled area to remove the stain and deactivate the odor. Simply spray a product such as PAWS - Pet Accident Washup Solution or Bio-OX Citrus Concentrate on the soiled area, and then allow it to penetrate for approximately five minutes. Using a clean white absorbent cloth, blot the area, pressing down firmly (do not rub) for 30 seconds. Repeat this blotting process until the area is dry. If the odor persists, repeat the process. PAWS will do an excellent job on old pet stains and odors too.
You can also try saturating the area with a 3% hydrogen peroxide solution. Let it sit for a few minutes. Then, using a clean white absorbent cloth, blot the area, pressing down firmly (do not rub) for 30 seconds. Repeat this blotting process until the area is dry. If the odor or stain persists, repeat the process.
Another option is baking soda, which can be used to eliminate surface (but not deeply penetrated) odors. Dampen the area with clean water and then sprinkle baking soda over it. Rub the baking soda into the soiled area and let dry; brush or vacuum to remove the dry material.
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