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Here's a window cleaning tip for smokers: To remove a smoke film from your blinds, wipe each slat with a sponge dipped in a vinegar water solution. This window cleaning solution will also remove the odors associated with smoking.
When you say Vinegar, do you mean Apple Cider or White?
WHITE vinegar is what's used for cleaning and deodorizing. Apple cider vinegar is generally used for health tonics and such, and would actually leave a brown stain. Though perhaps a better tip for keeping your blinds (and everything else) looking and smelling cleaner is by not smoking in the house in the first place.